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Measuring Electric Fields and Noncovalent Interactions Using the Vibrational Stark Effect
Organic Chemicals Proteins Vibration Models,Molecular Static Electricity
2016/5/25
Over the past decade, we have developed a spectroscopic approach to measure electric fields inside matter with high spatial (<1 Å) and field (<1 MV/cm) resolution. The approach hinges on exploiti...
Vibrational Stark Effects of Nitriles II. Physical Origins of Stark Effects from Experiment and Perturbation Models
platinum titania catalyst flame synthesis one-step oxidation screening
2016/5/23
Vibrational Stark effects, which are the effects of electric fields on vibrational spectra, were measured previously for the C−N stretch mode of several small nitriles, yielding difference dipol...